• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Granular crude brown coal or lignite is introduced into a pressure steaming chamber at a pressure above 1 MPa, where it is partially dehydrated by means of an evaporation agent, e.g. steam, pressure carbonized, uniformly shrunk and heated substantially uniformly to a temperature above 423 DEG K it is then conveyed without expansion to a pressure of less than 0.5 MPa into a pressure degasification and pressure gasification chamber, in which it will undergo further non-destructive drying as a result of its heat content, the pressure degasification and pressure gasification of the treated brown coal or lignite being subsequently effected.
    公开号:SU1041559A1
    申请号:SU797770802
    申请日:1979-09-18
    公开日:1983-09-15
    发明作者:Рихтер Херберт；Зеиферт Гюнтер；Баум Эберхард；Вернер Куринг；Бертхольд Кнаут；Гюнтер Шолц；Бертхолд Неуманн；Вилхельм Моттитшка；Вернер Хауптманн；Винфрид Боссон；Петер Модде
    申请人:Феб Газкомбинат Шварце Пумпе (Инопредприятие)；
    IPC主号:
    专利说明:

    7. Method according to paragraphs. 1 and 2, differing in that the steaming under pressure and the gasification under pressure are carried out in one apparatus, working under pressure.
    8. Method pop. 1-7, I differ by the fact that coal is cleaned from the smallest grains formed in the process of steaming by draining water directly formed in the process of steaming, and by feeding circulating water,
     It was obtained by steaming, above the upper level of coal loading.
    9. Method according to paragraphs. 1-8, characterized in that the water obtained in the steaming process is continuously withdrawn from the steaming chamber and used to produce steam or hot water.
    10. Method according to claims 1-9i and tl.ch that the water obtained in the steaming process is supplied: to an apparatus in which atmospheric pressure is maintained, and steam and / or hot water generated in the apparatus used to preheat a variety of brown i coal. .
    11. Method according to paragraphs. 1-10, about t. because the hot water produced at atmospheric pressure is used for hydrotransport with simultaneous heating of brown coal to the hopper connected to the apparatus in which the process is carried out.
    12. Method according to paragraphs. 1-3 and 7-9, differing in the fact that water obtained in the process of steaming under pressure is used for hydrotransport with simultaneous preliminary steaming of brown coal from the coal lock into the steaming chamber under pressure.
    13. Method according to paragraphs. 1-3, 7-10, and 12, characterized in that the regular brown coal is preheated in the coal sluice by a portion of the stream of steaming means and / or hot water produced in the steaming process.
    1. The method according to paragraphs. 1-13, characterized in that, for steaming under pressure, saturated or superheated steam is supplied to the steaming chamber.
    15. The method according to paragraphs. 1-1, which is based on the fact that the water vapor
    used as a steaming agent, is saturated at a pressure that is supported by steaming water obtained in the steaming process and fed to the steaming chamber above the coal load in an amount that provides an insignificant amount of residual steam that constantly comes along with coal gases in the gasification chamber.
    1b. The method according to paragraphs. 1-2, 7-15, about tl, and that the steam produced in the pressure jacket of the gasification apparatus is used for the steaming process under pressure. . .
    1. The method according to paragraphs. 1-13, characterized in that the steaming of the granular solid brown coal under pressure is carried out using hot saturated or superheated gases obtained by partially oxidizing the fuel at a partial pressure of water vapor above 1 MPa and containing water vapor; gases are continuously supplied to the dewatered coal, while the gas in the process of steaming under pressure condenses such amount of steam that the partial pressure of water vapor becomes higher than 0.5 MPa, and the gas containing water vapor is removed from the steaming chamber obtained in the process of steaming gases.
    18. Method according to paragraphs. 1, 2, 7 and 17, characterized in that the steaming under pressure, additional drying and gasification are carried out in one pressure apparatus, the crude gas obtained during gasification in the lower part of the apparatus is fed upwards to meet the movement of the coal load.
    19. Method according to paragraphs. 1, 2, 7, 17 and 18, characterized in that a part of water extracted from steaming under pressure of a thick brown coal is removed from the apparatus with the help of crude gas under pressure in the form of the smallest droplets.
    20. Method according to paragraphs. 1, 2, 7-13 and 17-19, characterized in that the water that accumulates between the steaming zones under pressure and the additional drying is discharged using appropriate devices.
    . 21, a method according to claim 17, characterized in that the gas obtained by partial oxidation of the fuel and containing water vapor is saturated and cleaned from the dust and condensed hydrocarbons contained in it before being fed into the steaming chamber under pressure.
    22. Method according to paragraphs. 17-21, characterized in that the crude gas containing water vapor used for steaming under pressure is saturated and cleaned of dust with water obtained in the process of steaming coal under pressure.
    23. Method according to paragraphs. 17 and 19-22, characterized in that hot gases obtained by partial oxidation of the fuel and containing water vapor and not containing pheno and overheated water vapor containing gases are introduced into the steaming chamber above the upper level of the coal charge.
    2. The method according to PP, 17-20, about tl and h and n and with ° the fact that in the gasification chamber for additional drying of coal dewatered by steaming under pressure of the grains, part of the raw gas stream obtained during gasification is fed.
    25. Method according to paragraphs. 17-20, 22 and 2, characterized in that a part of the gas stream used for additional drying in the gasification chamber and containing a small amount of dust in a large amount of hydrocarbons, is used for steaming under the pressure of a fine brown coal grain.
    26. Method according to claims. 17, 19-23, characterized in that a portion of the stream of raw gas obtained in the gasification chamber is withdrawn from the reduction zone as a pure, tarless gas, saturates and cleans it of dust and is used for steaming under pressure of brown coal.
    27. Method according to paragraphs. 17, 19-20, 232k and 26, characterized in that the clean gas is removed from the reduction zone at a temperature or part of the raw gas stream brought to a temperature at which the vapor contained in the gas fed to the steaming zone does not contain phenol.
    28. Method according to paragraphs. 17, 19, 21-23, and characterized in that after steaming the granular solid brown coal under pressure using hot, steam-oxidized gases containing water vapor, the pressure drops
    29. Method according to paragraphs. 1-6, 8-17, 19 and 22, 23, 2bi27, characterized in that the gasification process under pressure is carried out
    in a separate unit.
    30. Method according to paragraphs. 1-6, 8-17, 19-21, 22, 23, 26, 27 and 29, characterized in that the coke obtained after the gasification process under pressure is used as a smokeless fuel.
    31. Method according to paragraphs. 1-6, 8-17, 19-21, 22, 23, 26, 27, 29 and 30, characterized in that all or all of the coke produced is used in various gasification processes under pressure, and the gas or hours produced in these processes It is used as washing gas for gasification, further drying and steaming under pressure.
    32. Method according to paragraphs. 1-6, 8-17, 19, 21, 22, 23, 26, 27 and 23-31, characterized in that, by steaming under pressure, part of the ash is removed from the coal.
    The invention relates to a method for gasifying commercial brown coal, in particular loose brown coal, in which the drying of coal is directly connected to the gasification process of the fifth coal.
    pressure and energy consumption for the drying process is minimized.
    - Drying of granular rich brown coal with high water content.  J, in particular, friable brown coal, is carried out in such a way that there is no destruction of grains. Using this method, gasification of granular rich brown coal with a low coefficient of coalification in a fixed or vortex layer under pressure and formation of low-smoke low-grained fuel is obtained.  Brown coal, in particular loose brown coal, is used for gasification under pressure in a fixed or vortex layer.  When coal is used in the form of briquettes for r-azification under pressure in a fixed bed, coal preparation is expensive, associated with grinding, drying and briquetting.  At / high specific powers of the gasification process under pressure, the briquette does not withstand large thermal loads, and during drying and gasification in the gas generator, it disintegrates, which causes a large dust holding in the generating gas.  In the process of gasification under pressure using grains from,. loose brown coal.  In this case, the grains are dried outside the gas generator unit in tubular dryers.   .  .  The process of gasification under pressure with high performance, as well as the process of gasification without increased dust content in g-generator gas is carried out using dry grains of hard brown coal and using coal with loose brown coal dried in tubular dryers, the allowable dust content in the generator gas achieved with low gasification process productivity.  To increase the gasification process in a fixed bed, loose brown coal is used in the form of briquettes.  The use of briquettes requires a large amount of technical equipment, maintenance and repair of briquetting and drying installations.  Formation of large amounts of dust in case of environmental pollution and increase of the unit's high hazard.  The energy consumption for drying the coal by evaporation, heat losses with flue gases are high in these processes.  594 There are several technical solutions that partially eliminate the drawbacks associated with the use of loose brown coal in the gasification process.  A known method of moistening the gasifying material with ammonia water in front of the gas generator and / or in the gas generator to such an extent that the temperature of the gas at the exit from the fixed bed decreases.  There is a known method in which part of the produced gas is used to dry the fuel, and the other part of the gas is removed separately.  There is a method by which the amount of generating gas used for drying the fuel is controlled in such a way as to maintain a given heating rate in a certain temperature range.  Of 8. There are natural gasification methods in which the water content of the fuel used is increased: in briquettes on, in dry lumpy brown coal to it5%.  However, the known methods are not used in practice, since they are based on the use of briquettes or dried coal grains, which do not have sufficient strength in gasification under pressure.  In addition, known methods for making briquettes and dry grains require higher costs and plant maintenance.  So, for example, only cooking 1 kg of water from coal requires 3100-3300 kJ of heat. Hard brown coal is difficult to briquet.  Exodus from About 50 years ago, the method of drying solid lump brown coal was introduced, which became known as the pressure steaming method or the Fleissner method.  According to the Fleissner method, coal is heated under pressure with saturated steam.  In this method, the energy consumption for the release of water from coal is reduced.  Methods are known in which hot water and superheated steam are used instead of saturated steam.  These methods are mainly aimed at improving steam power supply.  The advantage of the method of steaming coal under pressure is the 8 LOW level of energy consumption in 1 001700 kJ / kg of released water.  The shortage of current compared to drying by convection is c. the need to use steam at a higher pressure, some of the water evaporates at a lower pressure and in a pressureless state.  This would entail a difference in water content and damage to the coal grain, but at a significantly lower level than during convection drying.  After treating the coal with this method, water reabsorption is possible only, to a minor extent, 3 the present time the method of steaming under pressure was introduced in practice only for hard brown coal or lignite. In the gasification process in a fixed bed under pressure, lignite was used which was pretreated water vapor in a pressure unit.  When steaming under the pressure of a briquetting soft brown coal, sludge is formed, which is a disadvantage of the method.  Steaming soft brown coal was carried out only for the purpose of producing dry coal for briquetting or as fuel for fireboxes.  It has been found that dewatering the coal to a water content below 30 is possible only at increased costs, and that the briquetting of the coal due to the steaming under pressure deteriorates.  For the rational use of waste heat. and the steaming method under pressure requires several high-pressure apparatuses interconnected by many technological pipelines.  After steaming, cooling of the neutralized coal is required.  A factor that increases installation costs is the discontinuity of the technological process.  In this connection, this method is material-intensive and requires high maintenance costs.  The environment is polluted by dust, which also increases the explosion hazard of the process.  The aim of the invention is to directly combine the drying of rich brown coal with a gasification process under pressure, as well as to reduce the consumption of thermal energy, the cost of process equipment and maintenance.  During gasification of brown coal under pressure, in particular soft brown coal, the disadvantage is the high dust content of the gas obtained during gasification under pressure.  The studies explain the decay of a briquette as follows.  The briquette agent is water contained in dry coal.  After evaporation of water, the adhesion forces in the briquette are broken.  Briquettes compressed from coarse-grained dry coal easily decompose under high thermal stress.  After heating to a temperature of 303313 K, the briquettes are fed to the gas generator, where the temperature reaches 523-773 K.  Temperature difference leads to uneven heating of the briquette.  Due to the fact that drying and shrinkage of the outer layers of the briquette is carried out faster than in the center of the briquette, stresses arise that accelerate the disintegration of the briquette.  In addition, the dry grains of briquette have a different moisture content, which is greater, the higher the average moisture content of the briquette.  When drying a briquette in a gas generator, these grains are reduced in size to varying degrees, which also "leads to the destruction of the briquette.  The decay of dry grains, especially dry grains of loose brown coal, is due to the following reason.  Drying of loose brown coal grains is carried out using convection drying, most often in tubular dryers when water evaporates.  Water evaporation Begins in the outer layers of the grain and then in the very core, the difference in moisture content between the upper layer and the core of the grain is observed at about 30.  As a result, the shrinkage of the outer layer is stronger than in the core, and the outer layer becomes loose and low-resistant to abrasion.  The large amount of steam produced during drying when passing through the grain mass of coal destroys the grain structure.  After drying by convection, before entering the generator set, the coal grains are cooled to 303-3 K.  Grains of coal dried by convection drying must be cooled in order to avoid coal self-ignition.  The cooled coal grains in the gas generators are heated instantly to K.  After d7 po grain. It is heated to the boiling point of water, instantly a strong shrinkage process begins, which begins in the upper layer and reaches the core.  This shrinking process leads to further destruction of the coal-oxide, which is already partially destroyed. in a dry rig.  The described phenomena are not observed or are observed only slightly when using hard or hard brown coal for the gasification process under pressure, which is caused by the shrinkage of these coals in natural fishery beds and low water content.  A direct technological link between steaming under pressure and gasification under pressure makes it possible to a large extent to avoid the above-mentioned drawbacks associated with known technical solutions.  According to the invention, this problem is solved as follows.  Granular solid brown coal, especially loose brown coal, with a moisture content intended for a gasification process under pressure, is transferred by a known method from a hopper using a sluice into a steaming chamber, in which the same pressure is maintained as in. gasification generator (above 1 MPa, mostly above 2 MPa).  Coarse brown coal is dewatered and carbonized under pressure in the steaming chamber by means of steaming, such as saturated steam.  The pre-dried hot coal is then transferred to a gasification generator, preferably without pressure drop and without cooling down to 23 K.  Due to the high heat content of the coal steamed under pressure in the gasification chamber, the coal is further dried, after which the coal is gasified.  In the process of steaming under the pressure of loose brown coal, only a small amount of the finest grains is formed and a small part of the large grains is distributed to the middle grains.  This phenomenon of decay does not have a negative effect on the gasification process under pressure, since dehydrated grains have a high wear resistance.  Water released during steaming. Coal under pressure is searching for 598 coal from the smallest grains.  - This cleaning effect can be enhanced by spraying hot water obtained and circulating during the steaming process in the upper part of the steaming chamber.  The steam that is used for steaming under pressure is saturated at the selected pressure and is fed into the steaming chamber above the average level of coal in such an amount that a small amount of steam along with the gases formed during carbonization enters the gasification chamber.  Water vapor may enter the gasification chamber in the overheated state.  It has been established that the bulk of the water from the rich brown coal, especially loose brown coal, is emitted at the beginning.  steaming and therefore does not require prolonged steaming at an appropriate pressure to release residual water.  Dehydrated and heated coal in the gasification chamber withstands subsequent loads of additional drying and heating without any special damage.  Rough brown coal is uniformly heated by steaming under pressure to a temperature or higher than, which, under the given technological conditions, boils water, however, at least 423 K.  The process of shrinking COAL occurs evenly and ends before the coal is supplied to the gasification chamber.  If the coal has an increased moisture content (), this is not a significant disadvantage.  The water vapor formed during the additional drying in the gasification chamber has a small volume as compared with its volume at atmospheric pressure and can pass through the coal mass without loosening its structure.  The evaporation of water from the core to the upper layer of the grain as a continuation of the steaming process takes place in liquid form at the temperature of the grain, which ranges from k23 K to the boiling point at the selected pressure of the process.  Since the pre-dried coal is fed into the gasification chamber without cooling and contact with air, the surface of the grain does not oxidize or solidify, but remains plastic. .  Therefore, the escape of steam from the core to the upper layer of grain with 9 dried in the gasification chamber is not jammed.  Water reabsorption cannot occur.  The heat supplied to the degassing and gasification chambers with hot coal steamed under pressure is sufficient for additional drying with a moisture content of up to a moisture content of 20%.  Thus, additional heat enters the gasification chamber with steamed coal.  Incomplete dewatering of the coal during steaming under pressure reduces the steaming time and reduces the size of the steaming chamber.  It has been established that coal dehydrated under pressure during gasification under pressure is not significantly destroyed compared to briquettes, and the resulting dewatered carbon coke has a higher wear resistance.  This makes it possible to supply coal dehydrated under pressure of grain to the gasification zone without significant damage.  Water obtained by steaming under pressure is converted into steam at atmospheric pressure.  Steam, as well as hot water, is used to preheat solid brown coal to 373 K.  The water obtained in the steaming process can be used to produce hot water.  Hot water can be used to hydrotransport rich brown coal to the bunker, and pressurized water obtained in the steaming process can be used to transport the rich brown coal from the coal sluice to the steaming chamber in front of the gasification generator.  In the latter case, the pre-steaming of the coal with hot water occurs.  In order to reduce the structural dimensions of the npori rivani chamber, a preliminary is advisable. but to process the regular brown coal in the sluice with a partial flow of the steaming agent or hot water obtained by steaming.  When pre-drying a variety of brown coal according to the invention, the need for heat when using the water obtained by steaming to heat the range brown coal. to ZbZ K is 1,000,1,200 kJ per 1 kg of water released during production and steam pressure and, in the same way, it is lower than in autonomous pressure-steaming installations.  This advantage is based on the fact that the heat of the steamed coal is fully utilized in the gasification process or in subsequent installations using heat from the exhaust gases.  Due to the fact that the steaming process is carried out continuously, there are no heat losses caused by the cooling of the steaming chamber.  The method according to the invention makes it possible to combine the steaming process under pressure with the gasification process in a large pressure apparatus.  Combining the steaming and gasification processes eliminates the loading, unloading, removal of carbon dioxide, and coal cooling devices.  An additional steam line for the steam steaming process carried out in the generator is not required, since the gasification process gas line can be used.  Gasification generators have a water jacket to protect the outer shell under pressure.  The water vapor produced in the water jacket can be used in the steaming process under pressure.  This process prevents the pollution of the environment with coal dust and reduces the explosion hazard of the process.  When used. Using briquettes for gasification, losses during briquetting are 3, - and losses due to dust removal in the gasification process under pressure of 10-15%.  This dust falls mainly in the form of sludge.  The amount of sludge produced according to the method of the invention depends on the individual stages of the process, but does not exceed the amount of sludge formed in the processes using briquettes.  In the proposed method, coals having a high ash content and which cannot be used for briquetting can be used.  due to high wear.  In the process of steaming under pressure part of the ash. , especially fine particles, washed away with the water produced. in the process of steaming.  Rough brown coal treated by the method according to the invention has good flowability, which improves the backfill movement in the generator and avoids the formation of channels and partitions that, during gasification, lead to increased dust removal. According to the invention, several sluice and steaming chambers under pressure are connected to the gasification generator, which in turn supply the degassing and gasification generator with hot, pre-dried coal.  In this variant of the technology, the disadvantage that is due to the fact that the increased heat and energy consumption is obsolete is eliminated by the fact that there is no need to observe the uniform movement of the backfill in the steaming chamber 5, there is no difficulty in extracting water obtained from the other. steaming and steaming under pressure can be carried out at a higher or lower pressure than in the gasification chamber.  If it is necessary to obtain a very dry fuel for the gasification process under pressure, then after partial: steaming under pressure with saturated steam, additional drying is performed with superheated steam.  In order to speed up the dewatering process, it is possible with this variant to work with steaming under pressure with a large amount of saturated steam.  At the same time, the steam flow rate in the coal bed and the heat transfer to the coal increase.  Residues of steam containing carbon dioxide and superheated steam used for drying fuel with overheated steam are used as gasification tools.  The raw gas obtained in the course of gasification under pressure is a hot and highly saturated water vapor and can be used as a means for steaming under pressure.  The raw gas, saturated with water vapor, after cleaning from dust and condensed hydrocarbons, has the high temperature necessary for the steaming process.  The use of raw gas produced in the process of gasification under pressure makes it possible to simplify the combination of methods of steam and gasification under pressure.  Solid brown coal, especially loose brown coal, is fed into the chamber, where the process of steaming under pressure and the gasification process under pressure take place.  Untreated gas, which is formed in the lowermost part of the chamber due to partial combustion of coal in a fixed bed, passes upward to meet the movement of the coal, performs its additional drying and steaming under pressure, and then is discharged through the upper part of the chamber.  Water, obtained in the process of steaming under pressure, saturates the crude gas coming from the zone of additional drying.  The amount of water released by steaming under the pressure of a rich brown coal, and especially soft brown coal, is usually greater than the amount of water needed to saturate the raw gas.  Depending on the selected process parameters, a portion of the excess water is discharged from the generator with unpurified gas in the form of a mist.  The remaining part of the water enters the zones of additional drying and evaporates, absorbing heat.  The latter leads to an increase in fuel consumption and gasification means.  To prevent an increase in the consumption of fuel and gasification means between the steaming zone and the additional drying zone, it is necessary to use water removal devices.  Due to this, it is possible to spray in the upper part of the circulating water chamber, thus increasing the degree of gas purification from fine dust formed during the steaming process.  Hydrocarbons condensed as a result of cooling the crude gas during the steaming process, improve the movement of the backfill in the steaming chamber, which prevents the formation of channels or partitions in subsequent zones.  Only a small fraction of the water vapor contained in the crude gas condenses on steaming under pressure, so that the crude ha can be cooled slightly.  Therefore, it is possible and rational to use the unpurified gas after it leaves the generator to produce steam due to the heat escaping with the unpurified gas.  The amount of heat required for pre-drying brown coal in the steaming zone under pressure up to ZbA K, grows to about 550-650 kJ / kg allocated when steaming water, and this is the amount of heat intended for steam production, comes with unclean gas leaving generator-.  Thus, there is no need to use high pressure steam. Extremely low heat demand for coal drying is due to the fact that heat loss from heated coal and hot condensate obtained in the process of steaming under pressure is absent in the combined process of steam steaming and gasification under pressure.  In the method according to the invention, the coal charge stream, steamed under pressure with a mixture of vapor and gas components of the raw gas, is continuous, thus accelerating the heating rate of coal, the chemical process of carbonization and the removal of the resulting gas components and, thereby, accelerates the entire dewatering process.  These benefits are also observed with the use of hot water containing ones.  steam, and in particular without phenolic unpurified gases produced in other processes of partial oxidation of fuel under pressure.  Since the process of steaming under pressure requires only a small part of the vapor contained in the raw gas, it is possible to use part of the raw gas obtained in the combined gasification process to steam the coal under pressure. At that, the partial pressure of the raw gas used for the steam under pressure can not exceed the partial pressure water vapor pressure corresponding to 0.5 MPa.  For additional drying of the fuel, only a fraction of the resulting crude gas, the so-called Schwelgas, is used.  the remaining part of the gas obtained during gasification is released as tarless, so-called clean gas.  When using loose brown coal in Scheelgas, low dust content / holding, and clean gas has high dust content.  The separation of the resulting crude gas into two streams allows the heating rates in the additional drying zones to be controlled, affecting the further processing of the fuel.  Due to low dust content; After saturation, the gasoline gas can be used for steaming under pressure and washing the coal bed from bottom to top.  The advantage of using only pure gas for properization under pressure is that it comes out of the reduction zone at a high temperature and is phenolic-free, and the water obtained by steaming does not require treatment in a phenol purification unit.  At the same time, clean gas must be introduced into the steaming chamber above the coal loading level of cleaning the dust from saturation with water.  When using a common generator for the processes of both pressurization and gasification, gas outlet means are located between the steaming zones of the pressure and the additional drying.  If the shwelgaz and pure gas are separated, it is possible to combine these two gases and use them for steaming under pressure.  At the same time, it is necessary to clean dust and saturate with pure gas obtained in the process of steaming before combining with shvelgas or mixed gas obtained after combining shwelgase and pure gas.  To speed up the dehydration process. when steaming under pressure, it is possible to feed the crude gas or part of the crude gas into the chamber, steaming under pressure in a superheated state.  It is possible to heat part of the crude gas to such a high temperature that the impurities contained in it are destroyed and the stream, after being saturated with water, can be used for steaming under pressure.  In accordance with the proposed method after gasification under pressure. They get durable coke.  A solid, smokeless solid fuel is further dried by a hot rinsing gas containing a large amount of moisture, and then steaming under pressure.  The carbonated fuel is cooled and can be used as coke.  The resulting coke or part of it can be used to carry out gasification under pressure in a separate apparatus, and the resulting gas or suit can be used for additional drying and steaming under the divide.  PRI me R 1.  An ordinary stormy angle with a grain size of mm, a moisture content of 57% and a temperature of about 293 K is fed to the bunker and heated to ZBZ K by steam or clear water by spraying water.  From the bunker, the regular brown coal is fed into the gateway, which is maintained at a pressure of 2.5 MPa, and is directed through the sluice into the steaming chamber under a pressure of 2.5 MPa, and is directed through the sluice into the steaming chamber under pressure. heating of brown coal to K with the help of a part of the steaming means flow or with the help of hot water obtained in the process of steaming and having a temperature of +90 K.  Steam is introduced into the steaming chamber under pressure with a temperature K through an opening above the coal charge.  The indicated temperature of the steaming agent allows the brown coal to be dewatered to 25% moisture content in 6090 minutes.  With the dewatering of brown coal to 35, the steaming time can be reduced to min.  This allows the structural dimensions of the pressure steaming chamber to be reduced.  The water released from the coal and condensing from the steaming agent is removed from the pressure steaming chamber using an appropriate device.  At the same time, the water washes away the smallest grains that form.  This cleaning effect is enhanced by spraying water into the steaming chamber under pressure by circulating water produced in the steaming process and having a temperature of about 90 K.  The dehydrated coal is evenly heated to 70-500 K and is fed continuously with notoKOM into the additional drying and gasification chamber.  The pressure in this chamber is 2.5 MPa.  Unlike the conventional method of “entering fuel with parameters of 303 K and 20% of water, boiled coal under pressure adds additional heat to the gasification generator about 370 kJ per t kg of dry coal with a moisture content of 20%. This heat is sufficient for drying coal from 35 to 20% moisture content without taking this heat from the gasification process.  Then the drying of coal occurs approximately 81% due to heat. Approximately 66 of them are exposed to steaming under pressure due to the release of water in liquid form in the steaming chamber under pressure; about 15% due to evaporation of gasification under pressure in the reactor and 19% due to evaporation as a result of thermal exposure during gasification under pressure.  Due to the fact that the pieces of coal enter the gasification reactor in a uniformly heated state and without destruction caused by uneven moisture content in the core and in the upper layer of the coal grain, and also without the influence of atmospheric air causing the coal surface to harden, and since the coal is additionally dried in the reactor at a pressure of 2.5 MPa (steam volume is about 1/21 volume at atmosphere) drying occurs without destroying the coal grains.  Excessive hot water, obtained in the process of steaming with a temperature of about 90 K at atmospheric pressure, is converted into hot steam with a temperature of about 373 K.  In addition, the resulting hot water is used to heat the solid brown coal used up to about 3,000 C.  Steam obtained at 2.5 MPa and kS5 K is used as a steaming agent.  If the steam has a higher pressure and a higher temperature, then the net will reduce the pressure when entering the chamber, and the steam is saturated with steaming water.  The heat demand in the steaming chamber is VET kJ per 1 kg of released water.  Steam consumption is regulated so that only a small amount of steam along with carbon dioxide formed during carbonation under pressure enters the gasification chamber.  The resulting steaming water has a low phenol content.  EXAMPLE 2.  Rough brown coal with a grain size of 5-60 mm and a moisture content of up to 57% is supplied using water obtained by an evaporation process and having a temperature of RF of 370 K to the gasification unit bunker and is heated to K.  From the buffer, coal is fed through a coal gateway into a large pressure vessel, in the lower part of which coal is gasified in a fixed bed at a pressure of 2.5 MPa.  The resulting gas goes upstream to the coal from the bottom up and passes in order the following zones: the zone of formation of ash, the zone of oxidation, the zone of recovery, the zone of additional drying the zone of steaming.  The water formed in the steaming zone saturates and supersatisfies the rising crude gas until it forms a mist.  Excessive water pr parivani. enters the subsequent zones and takes heat from them necessary for evaporation.  Due to the evaporation of the water, the steaming increases. .  oxygen and fuel consumption. , in the gasification process, the content of steam and CO in the produced gas is increased.  To eliminate these drawbacks between the steaming zones under pressure and additional drying, the mont. Devices for separating the water expelled from. coal in the process of parivani.  Exhaust water takes out a part of the dust obtained in the process of steaming and contained in the gas.  Water obtained in the process of steaming after. pressure relief. used for hydrotransport of commercial brown coal to the bunker.  Loose brown coal is dewatered in the steaming chamber to approximately 35% content and in the subsequent zones is further dried and gasified.  Untreated gas removes.  c from the top of the pressure vessel and its heat is used to produce steam.  In this example, the unpurified gas produced in the fixed bed gasification process at 2.5 MPa and K is used as a means of evaporation after saturation with water vapor.  Saturated crude gas has a moisture content of 1.6 kg of water per 1 meter of gas under normal conditions.  Heat consumption in the steaming zone is approximately 580 kJ | per 1 kg of allocated water.  After the steaming step, the raw gas has a temperature of kbQK and a moisture content of about 1.3 kg of water and 1 m of gas under normal conditions.  Steam is formed by the heat of the crude gas (steam has a pressure of 0.5 MPa) in the steaming step.  Charcoal loading is constantly reversed. It is supplied with raw gas, which leads to a rapid heating of the coal and a rapid removal of C02 and this allows sokra. Stamping time steaming. Hydrocarbons condensable from crude gas improves loading movement.  .  .   .  The disadvantages of this example include the high content of phenol in the steaming water, which leads to an additional loading of the device for purifying water from phenol by about 50.  Changes in the parameters of the crude gas in the steaming zone indicate.  that only insignificantly. The flax portion of the vapor contained in the raw gas is required for. steaming under pressure.  This allows only a portion of the untreated pelvis to be used for the steaming step, with the following options possible.  From the reduction zone of gasification in a fixed bed, a high-temperature, ground-free and phenolic-free pure gas is taken.  The clean gas is saturated with water, cleaned of dust as needed, and then sent to a pressurized vessel above the upper level of the coal charge for steaming under pressure.  It moves in the direction of the coal through the steaming zone and is withdrawn from the pressure vessel, together with the shwelgaz between the steaming zones under pressure and additional drying.  Additional load in the cleaning installation. water steaming from phenol is missing.  When using dust-free svellage for steaming under pressure, the shovel gas is supplied to meet the movement of the coal from the additional drying zone to the steaming zone under pressure, where it is saturated with water obtained during the steaming process and leaves the propelling zone under pressure above the coal loading level; Steaming water has a high content of phenol.  The condensed hydrocarbons improve the engine load and are partially discharged along with the water obtained in the steaming process and containing fine dust.  PRI me R 3.  An ordinary brown corner with grain sizes of 5–12 mm, moisture content up to 57% and preheated to 36 K is fed from the hopper alternately into two devices operating under pressure.  In the apparatus, the following functions are performed: coal is treated in the vessel with steam at 10 MPa and dehydrated by steaming for 15 minutes at a temperature of 583 K to 35%.  moisture content; recovered in the steaming process; the pressure is triggered up to 2.5 MPa, corresponding to the pressure in the generator located under the steaming chambers; coal is fed into the generator of the above vessels in turn; coal is fed to the gasification stage under pressure.  In the gasification chamber, additional drying is carried out with flushing gas obtained by gasification under pressure in a vortex layer.  The coke thus obtained is dosed to the gasification stage under pressure in the vortex layer.  After dusting, the resulting heated gas is directed to use its heat partially as flushing the gas into the stage, further drying.  Example.  An ordinary brown corner with an O-BO mm grain size and a moisture content of up to 5b is heated in a bunker to 3hz K and fed to a coal lock, from which coal is supplied to the steaming chamber under pressure with hot water at a temperature of 3 MPa.  In the feed process, the coal is pre-dewatered to a moisture content of 8%.  In the pressure steaming chamber, the coal is separated from the transporting liquid and steamed with saturated steam at a pressure of 2.5 MPa to a moisture content of 35%.  The water obtained in the steaming process is discharged together with the transport water. Part of this hot water, having a jeMnepaTypy of 5 K, from water and vehicle, along with fine dust, into a hydrocyclone.  A pressure of 3 MPa and a temperature of 503 K are maintained in the upper part of the hydrocyclone using a pressure boosting pump and a heat exchanger.  Water from a hydrocyclone is used for hydrotransport of a wide brown coal.  The coal, dried to a 35% moisture content, is supplied from the steaming chamber under pressure to the gas generator.  Where it is additionally dried. washing gas, gasified at a temperature of 1000 K.  The resulting coke, after depressurization, is cooled — and used as smokeless fuel.  It is recognized as an invention according to the results of the examination carried out by the Office for the Invention of the German Democratic Republic.
    权利要求:
    Claims (32)
    [1]
    1. METHOD FOR GASIFICATION OF ROW GRANULAR LOCAL COAL, in the form of loose brown coal, including gasification of gasification coal. agent under pressure, which means that prior to the gasification step, raw grain coal is fed into a steaming chamber in which a pressure of> 1 MPa is maintained; in the steaming chamber, coal is dehydrated by heating under pressure; to a temperature less than 423 K by a steaming agent, heated coal is fed from the steaming chamber to the gasification chamber, in which additional drying of coal is carried out.
    [2]
    2. The method according to π. 1, on the fact that the pressure in the steaming chamber is maintained equal to the pressure in the gasification chamber, and before ; Variable coal is fed continuously from the steaming chamber to the gasification chamber.
    [3]
    3. The method of pop. 1, it is distinguished by the fact that a higher or lower pressure is maintained in the steaming chamber during steaming, but not lower than 1 MPa than the pressure in the gasification chamber, and after steaming the coal in the steaming chamber, they create a pressure equal to the pressure in the gasification chamber, and coal is supplied to the gasification chamber periodically.
    [4]
    4. The method according to PP. 1 and 3, characterized in that the steaming of coal under pressure is carried out in one or more apparatuses and delivers coal from a hopper which is not under pressure, to the gasification apparatus operating under pressure, in the steaming chamber, the following operations are performed sequentially: depressurizing to atmospheric, feeding ordinary brown coal into the chamber, increasing the pressure to a pressure at which steaming, steaming under pressure, creating a pressure equal to the pressure in the gasification chamber, and partially dehydrated coal into the gasification chamber.
    [5]
    5. The method according to PP. 1 and 4, characterized in that the coal partially dehydrated by steaming under pressure is subjected to additional drying with superheated steam.
    [6]
    6. The method according to PP. 1, 4 and 5, characterized in that the steam obtained by steaming coal under pressure and containing CO 2 and the steam from the stage of additional drying of coal with superheated steam are used as gasification means.
    [7]
    7. The method according to PP. 1 and 2, which includes the fact that steaming under pressure and gasification under pressure is carried out in one apparatus operating under pressure.
    [8]
    8. The way popp. 1-7, it is distinguished by the fact that the coal is cleaned of the smallest grains formed during the steaming process by removing water directly formed during the steaming process and by supplying circulating water obtained by steaming above the upper level of the coal load.
    [9]
    9. The method according to PP. 1-8, characterized in that the water obtained during steaming is continuously withdrawn from the steaming chamber and used to produce steam or hot water.
    [10]
    10. The method according to PP. 1-9; about t l and -. characterized in that the water obtained during the steaming process is supplied to an apparatus in which atmospheric pressure is maintained, and the steam and / or hot water formed in the apparatus is used for preheating ordinary brown coal.
    [11]
    11. The way popp. 1-10, characterized in that the hot water obtained at atmospheric pressure is used for hydrotransport while heating ordinary brown coal to a feed hopper connected to the apparatus in which the process is carried out.
    [12]
    12. The method according to PP. 1-3 and 7 “9, characterized in that the water obtained in the process of steaming under pressure is used for hydrotransport with simultaneous preliminary steaming of ordinary brown coal from the coal sluice into the steaming chamber under pressure.
    [13]
    13. The method according to PP. 1-3, 7-Yu, and 1.2, characterized in that the ordinary brown coal is preheated in the coal sluice part of the flow of steaming means and / or hot water obtained in the process of steaming
    [14]
    14. The method according to PP. 1-13, characterized in that for steaming under pressure in the steaming chamber serves saturated or superheated water vapor. ’
    [15]
    15. The method according to PP. 1-14, wherein the water vapor used as a steaming agent is saturated at a pressure which is maintained by “steaming” with the water obtained in the steaming process and fed to the steaming chamber above the coal charge in an amount that provides an insignificant amount of residual steam, constantly entering together with the gases formed during coal coalification into the gasification chamber.
    [16]
    16. The method according to PP. 1-2, 7 * 15, which is related to the fact that the steam obtained in the water jacket of a pressure-operated gasification apparatus is used for pressure steaming.
    [17]
    17. The method according to PP. 1-13, characterized in that the steaming of ordinary ordinary brown coal under pressure is carried out at. the help of hot saturated or superheated gases obtained by partial oxidation of fuel at a partial pressure of water vapor above 1 MPa, and containing water vapor; gases are constantly supplied to dehydrated coal; at the same time, such a quantity of steam condenses from the gas during pressure steaming that the partial pressure of water vapor becomes higher than 0.5 MPa, and gas containing water vapor together with the gases obtained during the steaming is removed from the steaming chamber.
    [18]
    18. The method according to PP. 1,2, 7 and 17, characterized in that the steaming under pressure, additional drying and gasification are carried out in one apparatus operating under pressure, obtained by gasification in the lower part of the apparatus, the crude gas is fed upward towards the movement of the coal load.
    [19]
    19. The method according to PP. 1, 2, 7, .17 and 18, characterized in that | a portion of the water released by steam pressure of the ordinary brown coal is removed from the apparatus by means of crude gas operating under pressure in the form of tiny drops.
    [20]
    20. The method according to PP. 1, 2, 713 and 17 “19, characterized in that the water that accumulates between the zones of steaming under pressure and additional drying, is removed using appropriate devices.
    1θ4ΐ
    [21]
    21. The method according to π. 17, characterized in that the gas produced by partial oxidation of the fuel and containing water vapor before being fed into the steaming chamber under saturated pressure and purified from dust contained therein and condensed: rowan hydrocarbons.
    [22]
    22. The method according to PP, 17-21, characterized in that used for steaming under pressure, the crude gas containing water vapor, saturate and clean of dust from water obtained in the process of steaming coal under pressure.
    [23]
    23. The method according to PP. 17 and 19-22, characterized in that the hot gases obtained by partial oxidation of the fuel and containing water vapor and not containing phenol, and superheated gases containing water vapor are introduced into the steaming chamber above the upper level of the coal charge.
    [24]
    24. The method according to PP. 17-20 of τη and h and w and d w c * i 'in that the gasification chamber for further drying the dehydrated pressurized steaming coal grains fed part h of flow of the crude gas obtained by gasification.
    [25]
    25. The method according to PP. 17 “20, 22 and 24, characterized in that part of the gas stream used for additional drying in the gasification chamber and containing a small amount of dust in a large amount of hydrocarbons is used for steaming brown coal grains under pressure.
    [26]
    26. The method according to PP. 17, 19 “23, characterized in that a part of the stream of crude gas obtained in the gasification chamber is removed from the reduction zone in the form of a pure, tarless gas, it is saturated and cleaned of dust and used to steam ordinary brown coal under pressure.
    [27]
    27. The method according to PP. 17, 19 “20, 2324 and 26, characterized in that pure gas is removed from the reduction zone at a temperature or part of the raw gas stream is brought to a temperature at which the steam contained in the gas supplied to the steaming zone does not contain phenol.
    [28]
    28. The method according to PP. 17, 19, 21-23, and 25-27, characterized in that after steaming the granular ordinary brown coal under pressure with the help of hot gas containing water vapor, partial oxidation of the fuel relieve pressure.
    [29]
    29. The method according to PP. 1-6, 8-17, 19 “21 and 22, 23, 26 and 27, characterized in that the gasification process under pressure is carried out in a separate apparatus.
    [30]
    30. The method according to PP. 1-6, 8-17, 19-21, 22, 23, 26, 27 and 29, characterized in that the coke obtained after the gasification process under pressure is cooled and used as smokeless fuel.
    [31]
    31. The method according to PP. 1-6, 8-17, 19-21, 22, 23, 26, 27, 29 and 30, characterized in that all or part of the obtained coke is used in various gasification processes under pressure, and the gas or part obtained in these processes it is used as a flushing gas for gasification, additional drying and steaming under pressure ^.
    [32]
    32. The method according to PP. 1-6, 8-17, 19, 21, 22, 23, 26, 27 and 2931, characterized in that when steaming under pressure of ud part of the ash is extracted from coal.
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    同族专利:
    公开号 | 公开日
    PL127068B1|1983-09-30|
    JPS5589393A|1980-07-05|
    DD145180A3|1980-11-26|
    NL7906674A|1980-04-18|
    GB2035366B|1983-01-06|
    AU5163079A|1980-04-24|
    JPS5839471B2|1983-08-30|
    YU250179A|1983-02-28|
    PL218799A1|1980-06-16|
    GB2035366A|1980-06-18|
    IN152361B|1983-12-31|
    HU182961B|1984-03-28|
    ATA557779A|1983-10-15|
    DE2935594A1|1980-04-24|
    引用文献:
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    RU2513404C2|2009-01-28|2014-04-20|Уде Гмбх|Method of fuel supply for fluidised gasification reactor from storage hopper|
    RU2536644C2|2012-10-29|2014-12-27|Александр Алексеевич Концевой|Method of production of gaseous coolant and dry bulk material with it and device for implementation of said method|
    EA032663B1|2015-08-18|2019-06-28|Глок Экоенерги Гмбх|Method and device for drying wood chips|
    AT374491B|1982-01-20|1984-04-25|Voest Alpine Ag|METHOD FOR CONTINUOUS DRYING AND FINISHING OF ORGANIC SOLIDS, E.g. BROWN COALS|
    AUPS335902A0|2002-07-03|2002-07-25|Wesfarmers Premier Coal Limited|Coal drying and charring process|
    EP2675872A1|2011-02-17|2013-12-25|European Charcoal Ag|Generating carbon and combustible gases from brown coal|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DD20846578A|DD145180A3|1978-10-16|1978-10-16|METHOD FOR THE PRINTING AND GASIFICATION OF RAW BROWN COAL|
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